Methods of Providing Tunable Warm White Light

ABSTRACT

The present disclosure provides methods for generating tunable white light. The methods include using a plurality of LED strings to generate light with color points that fall within white, red, and yellow/green color ranges, with each LED string being driven with a separately controllable drive current in order to tune the generated light output.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of International Patent Applications PCT/US2016/015318 filed Jan. 28, 2016; PCT/US2016/015368 filed Jan. 28, 2016; PCT/US2016/015348 filed Jan. 28, 2016; PCT/US2016/015402 filed Jan. 28, 2016; and PCT/US2017/047233 filed Aug. 16, 2017, the contents of which are hereby incorporated by reference as if fully set forth herein.

FIELD OF THE DISCLOSURE

This disclosure is in the field of solid-state lighting. In particular, the disclosure relates to devices for use in providing tunable white light with high color rendering and circadian stimulus performance.

BACKGROUND

A wide variety of light emitting devices are known in the art including, for example, incandescent light bulbs, fluorescent lights, and semiconductor light emitting devices such as light emitting diodes (“LEDs”).

There are a variety of resources utilized to describe the light produced from a light emitting device, one commonly used resource is 1931 CIE (Commission Internationale de l'Eclairage) Chromaticity Diagram. The 1931 CIE Chromaticity Diagram maps out the human color perception in terms of two CIE parameters x and y. The spectral colors are distributed around the edge of the outlined space, which includes all of the hues perceived by the human eye. The boundary line represents maximum saturation for the spectral colors, and the interior portion represents less saturated colors including white light. The diagram also depicts the Planckian locus, also referred to as the black body locus (BBL), with correlated color temperatures, which represents the chromaticity coordinates (i.e., color points) that correspond to radiation from a black-body at different temperatures. Illuminants that produce light on or near the BBL can thus be described in terms of their correlated color temperatures (CCT). These illuminants yield pleasing “white light” to human observers, with general illumination typically utilizing CCT values between 1,800K and 10,000K.

Color rendering index (CRI) is described as an indication of the vibrancy of the color of light being produced by a light source. In practical terms, the CRI is a relative measure of the shift in surface color of an object when lit by a particular lamp as compared to a reference light source, typically either a black-body radiator or the daylight spectrum. The higher the CRI value for a particular light source, the better that the light source renders the colors of various objects it is used to illuminate.

LEDs have the potential to exhibit very high power efficiencies relative to conventional incandescent or fluorescent lights. Most LEDs are substantially monochromatic light sources that appear to emit light having a single color. Thus, the spectral power distribution (“SPD”) of the light emitted by most LEDs is tightly centered about a “peak” wavelength, which is the single wavelength where the spectral power distribution or “emission spectrum” of the LED reaches its maximum as detected by a photo-detector. LEDs typically have a full-width half-maximum wavelength range of about 10 nm to 30 nm, comparatively narrow with respect to the broad range of visible light to the human eye, which ranges from approximately from 380 nm to 800 nm.

In order to use LEDs to generate white light, LED lamps have been provided that include two or more LEDs that each emit a light of a different color. The different colors combine to produce a desired intensity and/or color of white light. For example, by simultaneously energizing red, green and blue LEDs, the resulting combined light may appear white, or nearly white, depending on, for example, the relative intensities, peak wavelengths and spectral power distributions of the source red, green and blue LEDs. The aggregate emissions from red, green, and blue LEDs typically provide poor CRI for general illumination applications due to the gaps in the spectral power distribution in regions remote from the peak wavelengths of the LEDs.

White light may also be produced by utilizing one or more luminescent materials such as phosphors to convert some of the light emitted by one or more LEDs to light of one or more other colors. The combination of the light emitted by the LEDs that is not converted by the luminescent material(s) and the light of other colors that are emitted by the luminescent material(s) may produce a white or near-white light.

LED lamps have been provided that can emit white light with different CCT values within a range. Such lamps utilize two or more LEDs, with or without luminescent materials, with respective drive currents that are increased or decreased to increase or decrease the amount of light emitted by each LED. By controllably altering the power to the various LEDs in the lamp, the overall light emitted can be tuned to different CCT values. The range of CCT values that can be provided with adequate CRI values and efficiency is limited by the selection of LEDs.

The spectral profiles of light emitted by white artificial lighting can impact circadian physiology, alertness, and cognitive performance levels. Bright artificial light can be used in a number of therapeutic applications, such as in the treatment of seasonal affective disorder (SAD), certain sleep problems, depression, jet lag, sleep disturbances in those with Parkinson's disease, the health consequences associated with shift work, and the resetting of the human circadian clock. Artificial lighting may change natural processes, interfere with melatonin production, or disrupt the circadian rhythm. Blue light may have a greater tendency than other colored light to affect living organisms through the disruption of their biological processes which can rely upon natural cycles of daylight and darkness. Exposure to blue light late in the evening and at night may be detrimental to one's health.

Significant challenges remain in providing LED lamps that can provide white light across a range of CCT values while simultaneously achieving high efficiencies, high luminous flux, good color rendering, and acceptable color stability. It is also a challenge to provide lighting apparatuses that can provide desirable lighting performance while allowing for the control of circadian energy performance.

DISCLOSURE

The present disclosure provides aspects of semiconductor light emitting devices comprising a first light emitting diode (“LED”) string that comprises a first LED that has a first recipient luminophoric medium that comprises a first luminescent material, a second LED string that comprises a second LED that has a second recipient luminophoric medium that comprises a second luminescent material, a third LED string that comprises a third LED that has a third recipient luminophoric medium that comprises a third luminescent material, and a drive circuit that is responsive to input from one or more of an end user of the semiconductor light emitting device and one or more sensors measuring a characteristic associated with the performance of the semiconductor light emitting device. In some implementations the first LED and first luminophoric medium together emit a first unsaturated light having a first color point within a white color range, the second LED and second luminophoric medium together emit a second unsaturated light having a second color point within a red color range, and the third LED and third luminophoric medium together emit a third unsaturated light having a third color point within a yellow/green color range. In some implementations the drive circuit is configured to adjust the relative values of first, second, and third drive currents provided to the LEDs in the first, second, and third LED strings, respectively, to adjust a fourth color point of a fourth unsaturated light that results from a combination of the first, second, and third unsaturated light. In some implementations of the devices of the present disclosure the red color range can be defined by the spectral locus between the constant CCT line of 1600K and the line of purples, the line of purples, a line connecting the ccx, ccy color coordinates (0.61, 0.21) and (0.47, 0.28), and the constant CCT line of 1600K, the yellow/green color range can be defined by the constant CCT line of 4600K, the Planckian locus between 4600K and 550K, the spectral locus, and a line connecting the ccx, ccy color coordinates (0.445, 0.555) and (0.38, 0.505), and the white color range can be defined by a polygonal region on the 1931 CIE Chromaticity Diagram defined by the following ccx, ccy color coordinates: (0.4006, 0.4044), (0.3736, 0.3874), (0.3670, 0.3578), (0.3898, 0.3716). In some implementations of the devices of the present disclosure the LEDs in the first, second, and third LED strings comprise blue LEDs having a peak wavelength between about 405 nm and about 485 nm. In some implementations the red color range comprises a region on the 1931 CIE Chromaticity Diagram defined by a 20-step MacAdam ellipse at 1200K, 20 points below the Planckian locus, the yellow/green color range comprises a region on the 1931 CIE Chromaticity Diagram defined by a 16-step MacAdam ellipse at 3700K, 30 points above Planckian locus, and the white color range comprises a single 5-step MacAdam ellipse with center point (0.3818, 0.3797) with a major axis “a” of 0.01565, minor axis “b” of 0.00670, with an ellipse rotation angle θ of 52.70°. In some implementations the devices of the present disclosure comprise a drive circuit is configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3200K, and in some of these implementations the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90 and R9 greater than or equal to about 55, one or more of Rf greater than or equal to 75, Rf greater than or equal to about 80, Rf greater than or equal to about 90, Rf greater than about 95, Rf equal to about 100, Rg greater than or equal to about 80 and less than or equal to about 120, Rg greater than or equal to about 90 and less than or equal to about 110, Rg greater than or equal to about 95 and less than or equal to about 105, or Rg equal to about 100. In some implementations the devices comprise a drive circuit configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3000K, and the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90 and R9 greater than or equal to about 60. In some implementations the devices comprise a drive circuit configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 2000K and about 3200K, and the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Rf greater than or equal to about 80, Rf greater than or equal to about 90, Rf greater than about 95, Rf equal to about 100, Rg greater than or equal to about 80 and less than or equal to about 120, Rg greater than or equal to about 90 and less than or equal to about 110, Rg greater than or equal to about 95 and less than or equal to about 105, or Rg equal to about 100.

The present disclosure provides aspects of methods of forming a light emitting apparatus, the methods comprising providing a substrate, mounting a first LED, a second LED, and a third LED on the substrate, providing first, second, and third luminophoric mediums in illuminative communication with the first, second, and third LEDs, respectively, wherein a combined light emitted by the first, second, and third LEDs and the first, second, and third luminophoric mediums together has a fourth color point that falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between 1800K and 3200K. In some implementations, the methods comprise providing a first LED and a first luminophoric medium configured to emit combined light having a first color point within a white color range defined by a polygonal region on the 1931 CIE Chromaticity Diagram defined by the following ccx, ccy color coordinates: (0.4006, 0.4044), (0.3736, 0.3874), (0.3670, 0.3578), (0.3898, 0.3716), providing a second LED and a second luminophoric medium configured to emit combined light having a second color point within a red color range defined by the spectral locus between the constant CCT line of 1600K and the line of purples, the line of purples, a line connecting the ccx, ccy color coordinates (0.61, 0.21) and (0.47, 0.28), and the constant CCT line of 1600K, and providing a third LED and a third luminophoric medium configured to emit combined light having a third color point within a yellow/green color range defined by the constant CCT line of 4600K, the Planckian locus between 4600K and 550K, the spectral locus, and a line connecting the ccx, ccy color coordinates (0.445, 0.555) and (0.38, 0.505). In some implementations, the methods comprise providing the first, second, and third LEDs and luminophoric mediums as phosphor-coated blue light emitting device chips. In some implementations the first, second, and third luminophoric mediums are provided in positions remotely located from the first, second, and third LEDs.

The general disclosure and the following further disclosure are exemplary and explanatory only and are not restrictive of the disclosure, as defined in the appended claims. Other aspects of the present disclosure will be apparent to those skilled in the art in view of the details as provided herein. In the figures, like reference numerals designate corresponding parts throughout the different views. All callouts and annotations are hereby incorporated by this reference as if fully set forth herein.

DRAWINGS

The summary, as well as the following detailed description, is further understood when read in conjunction with the appended drawings. For the purpose of illustrating the disclosure, there are shown in the drawings exemplary implementations of the disclosure; however, the disclosure is not limited to the specific methods, compositions, and devices disclosed. In addition, the drawings are not necessarily drawn to scale. In the drawings:

FIG. 1 illustrates aspects of light emitting devices according to the present disclosure;

FIG. 2 illustrates aspects of light emitting devices according to the present disclosure;

FIG. 3 depicts a graph of a 1931 CIE Chromaticity Diagram illustrating the location of the Planckian locus;

FIGS. 4A and 4B illustrate some aspects of light emitting devices according to the present disclosure, including some suitable color ranges for light generated by components of the devices;

FIG. 5 illustrates some aspects of light emitting devices according to the present disclosure, including some suitable color ranges for light generated by components of the devices;

FIG. 6 illustrates some aspects of light emitting devices according to the present disclosure, including some suitable color ranges for light generated by components of the devices;

FIG. 7 illustrates some aspects of light emitting devices according to the present disclosure, including some suitable color ranges for light generated by components of the devices;

FIG. 8 illustrates aspects of light emitting devices according to the present disclosure; and

FIG. 9 illustrates aspects of spectral power distributions suitable for color ranges of light generated by components of the devices of the present disclosure.

All descriptions and callouts in the Figures are hereby incorporated by this reference as if fully set forth herein.

FURTHER DISCLOSURE

The present disclosure may be understood more readily by reference to the following detailed description taken in connection with the accompanying figures and examples, which form a part of this disclosure. It is to be understood that this disclosure is not limited to the specific devices, methods, applications, conditions or parameters described and/or shown herein, and that the terminology used herein is for the purpose of describing particular exemplars by way of example only and is not intended to be limiting of the claimed disclosure. Also, as used in the specification including the appended claims, the singular forms “a,” “an,” and “the” include the plural, and reference to a particular numerical value includes at least that particular value, unless the context clearly dictates otherwise. The term “plurality”, as used herein, means more than one. When a range of values is expressed, another exemplar includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another exemplar. All ranges are inclusive and combinable.

It is to be appreciated that certain features of the disclosure which are, for clarity, described herein in the context of separate exemplar, may also be provided in combination in a single exemplary implementation. Conversely, various features of the disclosure that are, for brevity, described in the context of a single exemplary implementation, may also be provided separately or in any subcombination. Further, reference to values stated in ranges include each and every value within that range.

In one aspect, the present disclosure provides semiconductor light emitting devices 100 that can have a plurality of light emitting diode (LED) strings. Each LED string can have one, or more than one, LED. As depicted schematically in FIG. 1, the device 100 may comprise one or more LED strings (101A/101B/101C) that emit light (schematically shown with arrows). In some instances, the LED strings can have recipient luminophoric mediums (102A/102B/102C) associated therewith. The light emitted from the LED strings, combined with light emitted from the recipient luminophoric mediums, can be passed through one or more optical elements 103. Optical elements 103 may be one or more diffusers, lenses, light guides, reflective elements, or combinations thereof.

A recipient luminophoric medium 102A, 102B, or 102C includes one or more luminescent materials and is positioned to receive light that is emitted by an LED or other semiconductor light emitting device. In some implementations, recipient luminophoric mediums include layers having luminescent materials that are coated or sprayed directly onto a semiconductor light emitting device or on surfaces of the packaging thereof, and clear encapsulants that include luminescent materials that are arranged to partially or fully cover a semiconductor light emitting device. A recipient luminophoric medium may include one medium layer or the like in which one or more luminescent materials are mixed, multiple stacked layers or mediums, each of which may include one or more of the same or different luminescent materials, and/or multiple spaced apart layers or mediums, each of which may include the same or different luminescent materials. Suitable encapsulants are known by those skilled in the art and have suitable optical, mechanical, chemical, and thermal characteristics. In some implementations, encapsulants can include dimethyl silicone, phenyl silicone, epoxies, acrylics, and polycarbonates. In some implementations, a recipient luminophoric medium can be spatially separated (i.e., remotely located) from an LED or surfaces of the packaging thereof. In some implementations, such spatial segregation may involve separation of a distance of at least about 1 mm, at least about 2 mm, at least about 5 mm, or at least about 10 mm. In certain embodiments, conductive thermal communication between a spatially segregated luminophoric medium and one or more electrically activated emitters is not substantial. Luminescent materials can include phosphors, scintillators, day glow tapes, nanophosphors, inks that glow in visible spectrum upon illumination with light, semiconductor quantum dots, or combinations thereof.

In certain implementations, the recipient luminophoric mediums can be provided as volumetric light converting elements having luminescent materials dispersed throughout a volume of matrix material. Each volumetric light converting element can be provided within at least a portion of a reflective cavity disposed above a semiconductor light emitting device. In some implementations, each volumetric light converting element can be provided as spatially separated from the top surface of the associated semiconductor light emitting device, with a void or air gap between the volumetric light converting element and the associated semiconductor light emitting device. In other implementations, each volumetric light converting element can be provided within substantially all of a reflective cavity such that the bottom surface of each volumetric light converting element is adjacent to the top surface of the associated LED. In some implementations, an index matching compound can be provided between the adjacent surfaces to avoid any voids or air gaps between the surfaces so that the light emitted by the LED may pass from the LED to the volumetric light converting element with minimized reflection and refraction. Suitable implementations of volumetric light converting elements are more fully described in co-pending applications PCT/US2017/047217 entitled “Illuminating with a Multizone Mixing Cup”, and PCT/US2017/047224 entitled “Illuminating with a Multizone Mixing Cup”, filed contemporaneously with this application, the entirety of which are hereby incorporated by this reference as if fully set forth herein.

In some implementations, the luminescent materials may comprise phosphors comprising one or more of the following materials: BaMg₂Al₁₆O₂₇:Eu²⁺, BaMg₂Al₁₆O₂₇:Eu²⁺,Mn²⁺, CaSiO₃:Pb,Mn, CaWO₄:Pb, MgWO₄, Sr₅Cl(PO₄)₃:Eu²⁺, Sr₂P₂O₇:Sn²⁺, Sr₆P₅BO₂₀:Eu, Ca₅F(PO₄)₃:Sb, (Ba,Ti)₂P₂O₇:Ti, Sr₅F(PO₄)₃:Sb,Mn, (La,Ce,Tb)PO₄:Ce,Tb, (Ca,Zn,Mg)₃(PO₄)₂:Sn, (Sr,Mg)₃(PO₄)₂:Sn, Y₂O₃:Eu³⁺, Mg₄(F)GeO₆:Mn, LaMgAl₁₁O₁₉:Ce, LaPO₄:Ce, SrAl₁₂O₁₉:Ce, BaSi₂O₅:Pb, SrB₄O₇:Eu, Sr₂MgSi₂O₇:Pb, Gd₂O₂S:Tb, Gd₂O₂S:Eu, Gd₂O₂S:Pr, Gd₂O₂S:Pr,Ce,F, Y₂O₂S:Tb, Y₂O₂S:Eu, Y₂O₂S:Pr, Zn(0.5)Cd(0.4)S:Ag, Zn(0.4)Cd(0.6)S:Ag, Y₂SiO₅:Ce, YAlO₃:Ce, Y₃(Al,Ga)₅O₁₂:Ce, CdS:In, ZnO:Ga, ZnO:Zn, (Zn,Cd)S:Cu,Al, ZnCdS:Ag,Cu, ZnS:Ag, ZnS:Cu, NAI:Tl, CsI:Tl, ⁶LiF/ZnS:Ag, ⁶LiF/ZnS:Cu,Al,Au, ZnS:Cu,Al, ZnS:Cu,Au,Al, CaAlSiN₃:Eu, (Sr,Ca)AlSiN₃:Eu, (Ba,Ca,Sr,Mg)₂SiO₄:Eu, Lu₃Al₅O₁₂:Ce, Eu³⁺(Gd_(0.9)Y_(0.1))₃Al₅O₁₂:Bi³⁺,Tb³⁺, Y₃Al₅O₁₂:Ce, (La,Y)₃Si₆N₁₁:Ce, Ca₂AlSi₃O₂N₅:Ce³⁺, Ca₂AlSi₃O₂N₅:Eu²⁺, BaMgAl₁₀O₁₇:Eu, Sr₅(PO₄)₃C₁:Eu, (Ba,Ca,Sr,Mg)₂SiO₄:Eu, Si_(6-z)Al_(z)N_(8-z)O_(z):Eu (wherein 0<z≤4.2); M₃Si₆O₁₂N₂:Eu (wherein M=alkaline earth metal element), (Mg,Ca,Sr,Ba)Si₂O₂N₂:Eu, Sr₄Al₁₄O₂₅:Eu, (Ba,Sr,Ca)Al₂O₄:Eu, (Sr,Ba)Al₂Si₂O₈:Eu, (Ba,Mg)₂SiO₄:Eu, (Ba,Sr,Ca)₂(Mg, Zn)Si₂O₇:Eu, (Ba,Ca,Sr,Mg)₉(Sc,Y,Lu,Gd)₂(Si,Ge)₆O₂₄:Eu, Y₂SiO₅:CeTb, Sr₂P₂O₇—Sr₂B₂O₅:Eu, Sr₂Si₃O₈-2SrCl₂:Eu, Zn₂SiO₄:Mn, CeMgAl₁₁O₁₉:Tb, Y₃Al₅O₁₂:Tb, Ca₂Y₈(SiO₄)₆O₂:Tb, La₃Ga₅SiO₁₄:Tb, (Sr,Ba,Ca)Ga₂S₄:Eu,Tb,Sm, Y₃(Al,Ga)₅O₁₂:Ce, (Y,Ga,Tb,La,Sm,Pr,Lu)₃(Al,Ga)₅O₁₂:Ce, Ca₃Sc₂Si₃O₁₂:Ce, Ca₃(Sc,Mg,Na,Li)₂Si₃O₁₂:Ce, CaSc₂O₄:Ce, Eu-activated SrAl₂O₄:Eu, (La,Gd,Y)₂O₂S:Tb, CeLaPO₄:Tb, ZnS:Cu,Al, ZnS:Cu,Au,Al, (Y,Ga,Lu,Sc,La)BO₃:Ce,Tb, Na₂Gd₂B₂O₇:Ce,Tb, (Ba,Sr)₂(Ca,Mg,Zn)B₂O₆:K,Ce,Tb, Ca₈Mg (SiO₄)₄Cl₂:Eu,Mn, (Sr,Ca,Ba)(Al,Ga,In)₂S₄:Eu, (Ca,Sr)₈(Mg,Zn)(SiO₄)₄C₁₂:Eu,Mn, M₃Si₆O₉N₄:Eu, Sr₅Al₅Si₂₁O₂N₃₅:Eu, Sr₃Si₁₃Al₃N₂₁O₂:Eu, (Mg,Ca,Sr,Ba)₂Si₅N₈:Eu, (La,Y)₂O₂S:Eu, (Y,La,Gd,Lu)₂O₂S:Eu, Y(V,P)O₄:Eu, (Ba,Mg)₂SiO₄:Eu,Mn, (Ba,Sr, Ca,Mg)₂SiO₄:Eu,Mn, LiW₂O₈:Eu, LiW₂O₈:Eu,Sm, Eu₂W₂O₉, Eu₂W₂O₉:Nb and Eu₂W₂O₉:Sm, (Ca,Sr)S:Eu, YA₁O₃:Eu, Ca₂Y₈(SiO₄)₆O₂:Eu, LiY₉(SiO₄)₆O₂:Eu, (Y,Gd)₃Al₅O₁₂:Ce, (Tb,Gd)₃Al₅O₁₂:Ce, (Mg,Ca,Sr,Ba)₂Si₅(N,O)₈:Eu, (Mg,Ca,Sr,Ba)Si(N,O)₂:Eu, (Mg,Ca,Sr,Ba)AlSi(N,O)₃:Eu, (Sr,Ca,Ba,Mg)₁₀(PO₄)₆C₁₂:Eu, Mn, Eu,Ba₃MgSi₂O₈:Eu,Mn, (Ba,Sr,Ca,Mg)₃(Zn,Mg)Si₂O₈:Eu,Mn, (k-x)MgO.xAF₂.GeO₂:yMn⁴⁺ (wherein k=2.8 to 5, x=0.1 to 0.7, y=0.005 to 0.015, A=Ca, Sr, Ba, Zn or a mixture thereof), Eu-activated α-Sialon, (Gd,Y,Lu,La)₂O₃:Eu, Bi, (Gd,Y,Lu,La)₂O₂S:Eu,Bi, (Gd,Y, Lu,La)VO₄:Eu,Bi, SrY₂S₄:Eu,Ce, CaLa₂S₄:Ce,Eu, (Ba,Sr,Ca)MgP₂O₇:Eu, Mn, (Sr,Ca,Ba,Mg,Zn)₂P₂O₇:Eu,Mn, (Y,Lu)₂WO₆:Eu,Ma, (Ba,Sr,Ca)_(x)Si_(y)N_(z):Eu,Ce (wherein x, y and z are integers equal to or greater than 1), (Ca,Sr,Ba,Mg)₁₀(PO₄)₆(F,Cl,Br,OH):Eu,Mn, ((Y,Lu,Gd,Tb)_(1-x-y)Sc_(x)Ce_(y))₂(Ca,Mg)(Mg,Zn)_(2+r)Si_(z-q)Ge_(q)O_(12+δ), SrAlSi₄N₇, Sr₂Al₂Si₉O₂N₁₄:Eu, M¹ _(a)M² _(b)M³ _(c)O_(d) (wherein M¹=activator element including at least Ce, M²=bivalent metal element, M³=trivalent metal element, 0.0001≤a≤0.2, 0.8≤b≤1.2, 1.6≤c≤2.4 and 3.2≤d≤4.8), A_(2+x)M_(y)Mn_(z)F_(n) (wherein A=Na and/or K; M=Si and Al, and −1≤x≤1, 0.9≤y+z≤1.1, 0.001≤z≤0.4 and 5≤n≤7, KSF/KSNAF, or (La_(1-x-y), Eu_(x), Ln_(y))₂O₂S (wherein 0.02≤x≤0.50 and 0≤y≤0.50, Ln=Y³⁺, Gd³⁺, Lu³⁺, Sc³⁺, Sm³⁺ or Er³⁺). In some preferred implementations, the luminescent materials may comprise phosphors comprising one or more of the following materials: CaAlSiN₃:Eu, (Sr,Ca)AlSiN₃:Eu, BaMgAl₁₀O₁₇:Eu, (Ba,Ca,Sr,Mg)₂SiO₄:Eu, β-SiAlON, Lu₃Al₅O₁₂:Ce, Eu³⁺(Cd_(0.9)Y_(0.1))₃Al₅O₁₂:Bi³⁺, Tb³⁺, Y₃Al₅O₁₂:Ce, La₃Si₆N₁₁:Ce, (La,Y)₃Si₆N₁₁:Ce, Ca₂AlSi₃O₂N₅:Ce³⁺, Ca₂AlSi₃O₂N₅:Ce³⁺,Eu²⁺, Ca₂AlSi₃O₂N₅:Eu²⁺, BaMgAl₁₀O₁₇:Eu²⁺, Sr_(4.5)Eu_(0.5)(PO₄)₃Cl, or M¹ _(a)M² _(b)M³ _(c)O_(d) (wherein M¹=activator element comprising Ce, M²=bivalent metal element, M³=trivalent metal element, 0.0001≤a≤0.2, 0.8≤b≤1.2, 1.6≤c≤2.4 and 3.2≤d≤4.8). In further preferred implementations, the luminescent materials may comprise phosphors comprising one or more of the following materials: CaAlSiN₃:Eu, BaMgAl₁₀O₁₇:Eu, Lu₃Al₅O₁₂:Ce, or Y₃Al₅O₁₂:Ce.

Some implementations of the present invention relate to use of solid state emitter packages. A solid state emitter package typically includes at least one solid state emitter chip that is enclosed with packaging elements to provide environmental and/or mechanical protection, color selection, and light focusing, as well as electrical leads, contacts or traces enabling electrical connection to an external circuit. Encapsulant material, optionally including luminophoric material, may be disposed over solid state emitters in a solid state emitter package. Multiple solid state emitters may be provided in a single package. A package including multiple solid state emitters may include at least one of the following: a single leadframe arranged to conduct power to the solid state emitters, a single reflector arranged to reflect at least a portion of light emanating from each solid state emitter, a single submount supporting each solid state emitter, and a single lens arranged to transmit at least a portion of light emanating from each solid state emitter. Individual LEDs or groups of LEDs in a solid state package (e.g., wired in series) may be separately controlled. As depicted schematically in FIG. 2, multiple solid state packages 200 may be arranged in a single semiconductor light emitting device 100. Individual solid state emitter packages or groups of solid state emitter packages (e.g., wired in series) may be separately controlled. Separate control of individual emitters, groups of emitters, individual packages, or groups of packages, may be provided by independently applying drive currents to the relevant components with control elements known to those skilled in the art. In one embodiment, at least one control circuit 201 a may include a current supply circuit configured to independently apply an on-state drive current to each individual solid state emitter, group of solid state emitters, individual solid state emitter package, or group of solid state emitter packages. Such control may be responsive to a control signal (optionally including at least one sensor 202 arranged to sense electrical, optical, and/or thermal properties and/or environmental conditions), and a control system 203 may be configured to selectively provide one or more control signals to the at least one current supply circuit. In various embodiments, current to different circuits or circuit portions may be pre-set, user-defined, or responsive to one or more inputs or other control parameters. The design and fabrication of semiconductor light emitting devices are well known to those skilled in the art, and hence further description thereof will be omitted.

FIG. 3 illustrates a 1931 International Commission on Illumination (CIE) chromaticity diagram. The 1931 CIE Chromaticity diagram is a two-dimensional chromaticity space in which every visible color is represented by a point having x- and y-coordinates. Fully saturated (monochromatic) colors appear on the outer edge of the diagram, while less saturated colors (which represent a combination of wavelengths) appear on the interior of the diagram. The term “saturated”, as used herein, means having a purity of at least 85%, the term “purity” having a well-known meaning to persons skilled in the art, and procedures for calculating purity being well-known to those of skill in the art. The Planckian locus, or black body locus (BBL), represented by line 150 on the diagram, follows the color an incandescent black body would take in the chromaticity space as the temperature of the black body changes from about 1000K to 10,000 K. The black body locus goes from deep red at low temperatures (about 1000 K) through orange, yellowish white, white, and finally bluish white at very high temperatures. The temperature of a black body radiator corresponding to a particular color in a chromaticity space is referred to as the “correlated color temperature.” In general, light corresponding to a correlated color temperature (CCT) of about 2700 K to about 6500 K is considered to be “white” light. In particular, as used herein, “white light” generally refers to light having a chromaticity point that is within a 10-step MacAdam ellipse of a point on the black body locus having a CCT between 2700K and 6500K. However, it will be understood that tighter or looser definitions of white light can be used if desired. For example, white light can refer to light having a chromaticity point that is within a seven step MacAdam ellipse of a point on the black body locus having a CCT between 2700K and 6500K. The distance from the black body locus can be measured in the CIE 1960 chromaticity diagram, and is indicated by the symbol Δuv, or DUV. If the chromaticity point is above the Planckian locus the DUV is denoted by a positive number; if the chromaticity point is below the locus, DUV is indicated with a negative number. If the DUV is sufficiently positive, the light source may appear greenish or yellowish at the same CCT. If the DUV is sufficiently negative, the light source can appear to be purple or pinkish at the same CCT. Observers may prefer light above or below the Planckian locus for particular CCT values. DUV calculation methods are well known by those of ordinary skill in the art and are more fully described in ANSI C78.377, American National Standard for Electric Lamps—Specifications for the Chromaticity of Solid State Lighting (SSL) Products, which is incorporated by reference herein in its entirety for all purposes. A point representing the CIE Standard Illuminant D65 is also shown on the diagram. The D65 illuminant is intended to represent average daylight and has a CCT of approximately 6500K and the spectral power distribution is described more fully in Joint ISO/CIE Standard, ISO 10526:1999/CIE 5005/E-1998, CIE Standard Illuminants for Colorimetry, which is incorporated by reference herein in its entirety for all purposes.

The light emitted by a light source may be represented by a point on a chromaticity diagram, such as the 1931 CIE chromaticity diagram, having color coordinates denoted (ccx, ccy) on the X-Y axes of the diagram. A region on a chromaticity diagram may represent light sources having similar chromaticity coordinates.

The ability of a light source to accurately reproduce color in illuminated objects is typically characterized using the color rendering index (“CRT”), also referred to as the CIE Ra value. The Ra value of a light source is a modified average of the relative measurements of how the color rendition of an illumination system compares to that of a reference black-body radiator or daylight spectrum when illuminating eight reference colors R1-R8. Thus, the Ra value is a relative measure of the shift in surface color of an object when lit by a particular lamp. The Ra value equals 100 if the color coordinates of a set of test colors being illuminated by the illumination system are the same as the coordinates of the same test colors being irradiated by a reference light source of equivalent CCT. For CCTs less than 5000K, the reference illuminants used in the CRT calculation procedure are the SPDs of blackbody radiators; for CCTs above 5000K, imaginary SPDs calculated from a mathematical model of daylight are used. These reference sources were selected to approximate incandescent lamps and daylight, respectively. Daylight generally has an Ra value of nearly 100, incandescent bulbs have an Ra value of about 95, fluorescent lighting typically has an Ra value of about 70 to 85, while monochromatic light sources have an Ra value of essentially zero. Light sources for general illumination applications with an Ra value of less than 50 are generally considered very poor and are typically only used in applications where economic issues preclude other alternatives. The calculation of CIE Ra values is described more fully in Commission Internationale de l'Eclairage. 1995. Technical Report: Method of Measuring and Specifying Colour Rendering Properties of Light Sources, CIE No. 13.3-1995. Vienna, Austria: Commission Internationale de l'Eclairage, which is incorporated by reference herein in its entirety for all purposes. In addition to the Ra value, a light source can also be evaluated based on a measure of its ability to render a saturated red reference color R9, also known as test color sample 9 (“TCS09”), with the R9 color rendering value (“R9 value”). Light sources can further be evaluated by calculating the gamut area index (“GAI”). Connecting the rendered color points from the determination of the CIE Ra value in two dimensional space will form a gamut area. Gamut area index is calculated by dividing the gamut area formed by the light source with the gamut area formed by a reference source using the same set of colors that are used for CRI. GAI uses an Equal Energy Spectrum as the reference source rather than a black body radiator. A gamut area index related to a black body radiator (“GAIBB”) can be calculated by using the gamut area formed by the blackbody radiator at the equivalent CCT to the light source.

-   The ability of a light source to accurately reproduce color in     illuminated objects can be characterized using the metrics described     in IES Method for Evaluating Light Source Color Rendition,     Illuminating Engineering Society, Product ID: TM-30-15 (referred to     herein as the “TM-30-15 standard”), which is incorporated by     reference herein in its entirety for all purposes. The TM-30-15     standard describes metrics including the Fidelity Index (Rf) and the     Gamut Index (Rg) that can be calculated based on the color rendition     of a light source for 99 color evaluation samples (“CES”). The 99     CES provide uniform color space coverage, are intended to be     spectral sensitivity neutral, and provide color samples that     correspond to a variety of real objects. Rf values range from 0 to     100 and indicate the fidelity with which a light source renders     colors as compared with a reference illuminant. Rg values provide a     measure of the color gamut that the light source provides relative     to a reference illuminant. The range of Rg depends upon the Rf value     of the light source being tested. The reference illuminant is     selected depending on the CCT. For CCT values less than or equal to     4500K, Planckian radiation is used. For CCT values greater than or     equal to 5500K, CIE Daylight illuminant is used. Between 4500K and     5500K a proportional mix of Planckian radiation and the CIE Daylight     illuminant is used, according to the following equation:

${{S_{r,M}\left( {\lambda,T_{t}} \right)} = {{\frac{5500 - T_{t}}{1000}{S_{r,P}\left( {\lambda,T_{t}} \right)}} + {\left( {1 - \frac{5500 - T_{t}}{1000}} \right){S_{r,D}\left( {\lambda,T_{t}} \right)}}}},$

where T_(t) is the CCT value, S_(r,M)(λ, T_(t)) is the proportional mix reference illuminant, S_(r,P) (λ, T_(t)) is Planckian radiation, and S_(r,D)(λ, T_(t)) is the CIE Daylight illuminant.

The ability of a light source to provide illumination that allows for the clinical observation of cyanosis is based upon the light source's spectral power density in the red portion of the visible spectrum, particularly around 660 nm. The cyanosis observation index (“COI”) is defined by AS/NZS 1680.2.5 Interior Lighting Part 2.5: Hospital and Medical Tasks, Standards Australia, 1997 which is incorporated by reference herein in its entirety, including all appendices, for all purposes. COI is applicable for CCTs from about 3300K to about 5500K, and is preferably of a value less than about 3.3. If a light source's output around 660 nm is too low a patient's skin color may appear darker and may be falsely diagnosed as cyanosed. If a light source's output at 660 nm is too high, it may mask any cyanosis, and it may not be diagnosed when it is present. COI is a dimensionless number and is calculated from the spectral power distribution of the light source. The COI value is calculated by calculating the color difference between blood viewed under the test light source and viewed under the reference lamp (a 4000 K Planckian source) for 50% and 100% oxygen saturation and averaging the results. The lower the value of COI, the smaller the shift in color appearance results under illumination by the source under consideration.

Circadian illuminance (CLA) is a measure of circadian effective light, spectral irradiance distribution of the light incident at the cornea weighted to reflect the spectral sensitivity of the human circadian system as measured by acute melatonin suppression after a one-hour exposure, and CS, which is the effectiveness of the spectrally weighted irradiance at the cornea from threshold (CS=0.1) to saturation (CS=0.7). The values of CLA are scaled such that an incandescent source at 2856K (known as CIE Illuminant A) which produces 1000 lux (visual lux) will produce 1000 units of circadian lux (CLA). CS values are transformed CLA values and correspond to relative melotonian suppression after one hour of light exposure for a 2.3 mm diameter pupil during the mid-point of melotonian production. CS is calculated from

${CS} = {{0.7{\left( {1 - \frac{1}{1 + \left( \frac{CLA}{355.7} \right)^{\bigwedge 1.126}}} \right).}}}$

The calculation of CLA is more fully described in Rea et al., “Modelling the spectral sensitivity of the human circadian system,” Lighting Research and Technology, 2011; 0: 1-12, and Figueiro et al., “Designing with Circadian Stimulus”, October 2016, LD+A Magazine, Illuminating Engineering Society of North America, which are incorporated by reference herein in its entirety for all purposes. Figueiro et al. describe that exposure to a CS of 0.3 or greater at the eye, for at least one hour in the early part of the day, is effective for stimulating the circadian system and is associated with better sleep and improved behavior and mood.

Equivalent Melanopic Lux (EML) provides a measure of photoreceptive input to circadian and neurophysiological light responses in humans, as described in Lucas et al., “Measuring and using light in the melanopsin age.” Trends in Neurosciences, January 2014, Vol. 37, No. 1, pages 1-9, which is incorporated by reference herein in its entirety, including all appendices, for all purposes. Melanopic lux is weighted to a photopigment with max 480 nm with pre-receptoral filtering based on a 32-year-old standard observer, as described more fully in the Appendix A, Supplementary Data to Lucas et al. (2014), User Guide: Irradiance Toolbox (Oxford 18 Oct. 2013), University of Manchester, Lucas Group, which is incorporated by reference herein in its entirety for all purposes.

In some aspects the present disclosure relates to lighting devices and methods to provide light having particular vision energy and circadian energy performance. Many figures of merit are known in the art, some of which are described in Ji Hye Oh, Su Ji Yang and Young Rag Do, “Healthy, natural, efficient and tunable lighting: four-package white LEDs for optimizing the circadian effect, color quality and vision performance,” Light: Science & Applications (2014) 3: e141-e149, which is incorporated herein in its entirety, including supplementary information, for all purposes. Luminous efficacy of radiation (“LER”) can be calculated from the ratio of the luminous flux to the radiant flux (S(λ)), i.e. the spectral power distribution of the light source being evaluated, with the following equation:

${{LER}\left( \frac{lm}{W} \right)} = {683\left( \frac{lm}{W} \right){\frac{\int{{V(\lambda)}{S(\lambda)}d\; \lambda}}{\int{{S(\lambda)}d\; \lambda}}.}}$

Circadian efficacy of radiation (“CER”) can be calculated from the ratio of circadian luminous flux to the radiant flux, with the following equation:

${{CER}\left( \frac{b\; {lm}}{W} \right)} = {683\left( \frac{{lb}\; m}{W} \right){\frac{\int{{C(\lambda)}{S(\lambda)}d\; \lambda}}{\int{{S(\lambda)}d\; \lambda}}.}}$

Circadian action factor (“CAF”) can be defined by the ratio of CER to LER, with the following equation:

$\left( \frac{b\; {lm}}{lm} \right) = {\frac{{CER}\left( \frac{b\; {lm}}{W} \right)}{{LER}\left( \frac{lm}{W} \right)}.}$

The term “blm” refers to biolumens, units for measuring circadian flux, also known as circadian lumens. The term “lm” refers to visual lumens. V(λ) is the photopic spectral luminous efficiency function and C(λ) is the circadian spectral sensitivity function. The calculations herein use the circadian spectral sensitivity function, C(λ), from Gall et al., Proceedings of the CIE Symposium 2004 on Light and Health: Non-Visual Effects, 30 Sep.-2 Oct. 2004; Vienna, Austria 2004. CIE: Wien, 2004, pp 129-132, which is incorporated herein in its entirety for all purposes. By integrating the amount of light (milliwatts) within the circadian spectral sensitivity function and dividing such value by the number of photopic lumens, a relative measure of melatonin suppression effects of a particular light source can be obtained. A scaled relative measure denoted as melatonin suppressing milliwatts per hundred lumens may be obtained by dividing the photopic lumens by 100. The term “melatonin suppressing milliwatts per hundred lumens” consistent with the foregoing calculation method is used throughout this application and the accompanying figures and tables.

In some exemplary implementations, the present disclosure provides semiconductor light emitting devices 100 that include a plurality of LED strings, with each LED string having a recipient luminophoric medium that comprises a luminescent material. The LED(s) in each string and the luminophoric medium in each string together emit an unsaturated light having a color point within a color range in the 1931 CIE chromaticity diagram. A “color range” in the 1931 CIE chromaticity diagram refers to a bounded area defining a group of color coordinates (ccx, ccy).

In some implementations, three LED strings (101A/101B/101C) are present in a device 100, and the LED strings can have recipient luminophoric mediums (102A/102B/102C). A first LED string 101A and a first luminophoric medium 102A together can emit a first light having a first color point within a white color range. The combination of the first LED string 101A and the first luminophoric medium 102A are also referred to herein as a “white channel.” A second LED string 101B and a second luminophoric medium 102B together can emit a second light having a second color point within a red color range. The combination of the second LED string 101B and the second luminophoric medium 102B are also referred to herein as a “red channel.” A third LED string 101C and a third luminophoric medium 102C together can emit a third light having a third color point within a yellow/green color range. The combination of the third LED string 101C and the third luminophoric medium 102C are also referred to herein as a “yellow/green channel.” The first, second, and third LED strings 101A/101B/101C can be provided with independently applied on-state drive currents in order to tune the intensity of the first, second, and third unsaturated light produced by each string and luminophoric medium together. By varying the drive currents in a controlled manner, the color coordinate (ccx, ccy) of the total light that is emitted from the device 100 can be tuned. In some implementations, the device 100 can provide light at substantially the same color coordinate with different spectral power distribution profiles, which can result in different light characteristics at the same CCT. In some implementations, white light can be generated in modes that only produce light from one or two of the LED strings. In one implementation, white light is generated using only the first and second LED strings, i.e. the white and red channels. In another implementation, white light is generated using only the first and third LED strings, i.e., the white and yellow/green channels. In some implementations, only one of the LED strings, the white channel, is producing light during the generation of white light, as the other two LED strings are not necessary to generate white light at the desired color point with the desired color rendering performance.

FIGS. 4A and 4B depict suitable color ranges for some implementations of the disclosure. FIG. 4A depicts a yellow/green color range 303A defined by the constant CCT line of 4600K, the Planckian locus between 4600K and 550K, the spectral locus, and a line connecting the ccx, ccy color coordinates (0.445, 0.555) and (0.38, 0.505). FIG. 4B depicts a red color range 302A defined by the spectral locus between the constant CCT line of 1600K and the line of purples, the line of purples, a line connecting the ccx, ccy color coordinates (0.61, 0.21) and (0.47, 0.28), and the constant CCT line of 1600K. It should be understood that any gaps or openings in the described boundaries for the color ranges 302A, and 303A should be closed with straight lines to connect adjacent endpoints in order to define a closed boundary for each color range.

In some implementations, suitable color ranges can be narrower than those depicted in FIGS. 4A-4B. FIG. 5 depicts some suitable color ranges for some implementations of the disclosure. A red color range 302B can be defined by a 20-step MacAdam ellipse at a CCT of 1200K, 20 points below the Planckian locus. A yellow/green color range 303B can be defined by a 16-step MacAdam ellipse at a CCT of 3700K, 30 points above Planckian locus. FIG. 6 depicts some further color ranges suitable for some implementations of the disclosure. A red color range 302C is defined by a polygonal region on the 1931 CIE Chromaticity Diagram defined by the following ccx, ccy color coordinates: (0.53, 0.41), (0.59, 0.39), (0.63, 0.29), (0.58, 0.30). A yellow/green color range 303C is defined by a polygonal region on the 1931 CIE Chromaticity Diagram defined by the following ccx, ccy color coordinates: (0.37, 0.39), (0.33, 0.41), (0.43, 0.56), (0.54, 0.45).

The LEDs in the white channel can produce color points within acceptable color ranges 304A, 304B, and 304C. White color range 304A can be defined by a polygonal region on the 1931 CIE Chromaticity Diagram defined by the following ccx, ccy color coordinates: (0.4006, 0.4044), (0.3736, 0.3874), (0.3670, 0.3578), (0.3898, 0.3716), which correlates to an ANSI C78.377-2008 standard 4000K nominal CCT white light with target CCT and tolerance of 3985±275K and target duv and tolerance of 0.001±0.006, as more fully described in American National Standard ANSI C78.377-2008, “Specifications for the Chromaticity of Solid State Lighting Products,” National Electrical Manufacturers Association, American National Standard Lighting Group. In some implementations, suitable white color ranges can be described as MacAdam ellipse color ranges in the 1931 CIE Chromaticity Diagram color space, as illustrated schematically in FIG. 7, which depicts a color range 402, the black body locus 401, and a line 403 of constant ccy coordinates on the 1931 CIE Chromaticity Diagram. In FIG. 7, MacAdam ellipse ranges are described with major axis “a”, minor axis “b”, and ellipse rotation angle θ relative to line 403. In some implementations, the white color range can be range 304B, an embodiment of color range 402, and can be defined as a single 5-step MacAdam ellipse with center point (0.3818, 0.3797) with a major axis “a” of 0.01565, minor axis “b” of 0.00670, with an ellipse rotation angle θ of 52.70°, shown relative to a line 403. In some implementations, the white color range can be range 304C, an embodiment of color range 402, and can be defined as a single 3-step MacAdam ellipse with center point (0.3818, 0.3797) with a major axis “a” of 0.00939, minor axis “b” of 0.00402, with an ellipse rotation angle θ of 53.7°, shown relative to a line 403. FIG. 9 depicts a normalized spectral power distribution for a suitable white channel phosphor-coated LED, which can be LUXEON Z model LXZ1-4080, a 4000K nominal CCT 80 CRI LED.

In some implementations, the LEDs in the first, second and third LED strings can be LEDs with peak emission wavelengths at or below about 535 nm. In some implementations, the LEDs emit light with peak emission wavelengths between about 360 nm and about 535 nm. In some implementations, the LEDs in the first, second and third LED strings can be formed from InGaN semiconductor materials. In some preferred implementations, the first, second, and third LED strings can have LEDs having a peak wavelength between about 405 nm and about 485 nm. The LEDs used in the first, second and third LED strings may have full-width half-maximum wavelength ranges of between about 10 nm and about 30 nm. In some preferred implementations, the first, second, and third LED strings can include one or more LUXEON Z Color Line royal blue LEDs (product code LXZ1-PR01) of color bin codes 3, 4, 5, or 6 or one or more LUXEON Z Color Line blue LEDs (LXZ1-PB01) of color bin code 1 or 2 (Lumileds Holding B.V., Amsterdam, Netherlands). The wavelength information for these color bins is provided in Table 1. Similar LEDs from other manufacturers such as OSRAM GmbH and Cree, Inc. could also be used, provided they have peak emission and full-width half-maximum wavelengths of the appropriate values.

TABLE 1 Dominant/Peak Wavelength (nm) Part Number Bin Minimum Maximum LXZ1-PB01 1 460 465 2 465 470 5 480 485 LXZ1-PR01 3 440 445 4 445 450 5 450 455 6 455 460

In implementations utilizing LEDs that emit substantially saturated light at wavelengths between about 360 nm and about 535 nm, the device 100 can include suitable recipient luminophoric mediums for each LED in order to produce light having color points within the suitable red color ranges 302A-C, yellow/green color ranges 303A-C, and white color ranges 304A-C described herein. The light emitted by each LED string, i.e., the light emitted from the LED(s) and associated recipient luminophoric medium together, can have a spectral power distribution (“SPD”) having spectral power with ratios of power across the visible wavelength spectrum from about 380 nm to about 780 nm. While not wishing to be bound by any particular theory, it is speculated that the use of such LEDs in combination with recipient luminophoric mediums to create unsaturated light within the suitable color ranges 302A-C, 303A-C, and 304A-C provides for improved color rendering performance for white light across a predetermined range of CCTs from a single device 100. Some suitable ranges for spectral power distribution ratios of the light emitted by the LED strings (101B/101C) and recipient luminophoric mediums (102B/102C) together in the red and yellow/green channels are shown in Table 2. The table shows the ratios of spectral power within wavelength ranges, with an arbitrary reference wavelength range selected for each color range and normalized to a value of 100.0. Table 2 also shows suitable minimum and maximum values for the spectral intensities within various ranges relative to the normalized range with a value of 100.0, for the color points within the yellow/green (“yag”) and red color ranges. While not wishing to be bound by any particular theory, it is speculated that because the spectral power distributions for generated light with color points within the yellow/green and red color ranges contains higher spectral intensity across visible wavelengths as compared to lighting apparatuses and methods that utilize more saturated colors, this allows for improved color rendering for test colors other than R1-R8.

TABLE 2 Combined color Relative Spectral Power Distribution in 380-780 nm wavelength bins Channel point (ccx, ccy) 380-420 421-460 461-500 501-540 541-580 581-620 621-660 661-700 701-740 741-780 Red 1 (0.5842, 0.3112) 0.0 9.6 2.0 1.4 9.0 48.5 100.0 73.1 29.5 9.0 Red 2 (0.5842, 0.3112) 0.0 157.8 2.0 1.4 9.0 48.5 100.0 73.1 29.5 9.0 Red 3 (0.5702, 0.3869) 0.7 2.1 4.1 12.2 20.5 51.8 100.0 74.3 29.3 8.4 Red 4 (0.5563, 0.3072) 14.8 10.5 6.7 8.7 8.7 102.8 100.0 11.0 1.5 1.1 Red 5 (0.5941, 0.3215) 0.2 8.5 3.0 5.5 9.5 60.7 100.0 1.8 0.5 0.3 Red 6 (0.5842, 0.3112) 0.7 2.1 4.1 12.2 20.5 51.8 100.0 74.3 29.3 8.4 Red 7 (0.5735, 0.3007) 0.0 2.3 5.0 10.2 24.7 61.0 100.0 71.7 27.8 8.4 Red 8 (0.5700, 0.3870) 0.1 2.7 4.3 9.5 24.6 60.4 100.0 51.5 12.4 2.4 Red Minimum 0.0 2.1 2.0 1.4 8.7 48.5 100.0 1.8 0.5 0.3 Red Maximum 14.8 157.8 6.7 12.2 24.7 102.8 100.0 74.3 29.5 9.0 Yellow-Green 1 (0.4482, 0.5258) 1.0 1.1 5.7 75.8 100.0 83.6 69.6 40.9 15.6 4.7 Yellow-Green 2 (0.5108, 0.4708) 0.0 1.0 4.2 56.6 100.0 123.4 144.9 88.8 34.4 10.5 Yellow-Green 3 (0.3722, 0.4232) 1.0 25.3 52.7 77.5 100.0 80.5 62.0 35.1 13.3 4.0 Yellow-Green 4 (0.4494, 0.5161) 1.1 2.3 5.9 61.0 100.0 85.0 51.0 12.6 3.2 1.0 Yellow-Green 5 (0.4338, 0.5195) 0.8 5.6 6.3 73.4 100.0 83.8 48.4 19.5 6.5 2.0 Yellow-Green 6 (0.5108, 0.4708) 1.0 25.3 52.7 77.5 100.0 80.5 62.0 35.1 13.3 4.0 Yellow-Green 7 (0.5107, 0.4710) 0.2 0.9 5.0 58.9 100.0 129.4 140.5 91.6 35.3 10.5 Yellow-Green 8 (0.5107, 0.4710) 0.3 1.0 4.8 56.8 100.0 129.5 137.8 65.6 16.8 3.6 YAG Minimum 0.0 0.9 4.2 56.6 100.0 80.5 48.4 12.6 3.2 1.0 YAG Maximum 1.1 25.3 52.7 77.5 100.0 129.5 144.9 91.6 35.3 10.5

Blends of luminescent materials can be used in luminophoric mediums (102A/102B/102C) to create luminophoric mediums having the desired saturated color points when excited by their respective LED strings (101A/101B/101C) including luminescent materials such as those disclosed in co-pending applications PCT/US2016/015318 filed Jan. 28, 2016, entitled “Compositions for LED Light Conversions”, and PCT/US2016/015473 filed Jan. 28, 2016, entitled “Illuminating with a Multizone Mixing Cup”, the entirety of which are hereby incorporated by this reference as if fully set forth herein. Traditionally, a desired combined output light can be generated along a tie line between the LED string output light color point and the saturated color point of the associated recipient luminophoric medium by utilizing different ratios of total luminescent material to the encapsulant material in which it is incorporated. Increasing the amount of luminescent material in the optical path will shift the output light color point towards the saturated color point of the luminophoric medium. In some instances, the desired saturated color point of a recipient luminophoric medium can be achieved by blending two or more luminescent materials in a ratio. The appropriate ratio to achieve the desired saturated color point can be determined via methods known in the art. Generally speaking, any blend of luminescent materials can be treated as if it were a single luminescent material, thus the ratio of luminescent materials in the blend can be adjusted to continue to meet a target CIE value for LED strings having different peak emission wavelengths. Luminescent materials can be tuned for the desired excitation in response to the selected LEDs used in the LED strings (101A/101B/101C), which may have different peak emission wavelengths within the range of from about 360 nm to about 535 nm. Suitable methods for tuning the response of luminescent materials are known in the art and may include altering the concentrations of dopants within a phosphor, for example.

In some implementations of the present disclosure, luminophoric mediums can be provided with combinations of two types of luminescent materials. The first type of luminescent material emits light at a peak emission between about 515 nm and about 590 nm in response to the associated LED string emission. The second type of luminescent material emits at a peak emission between about 590 nm and about 700 nm in response to the associated LED string emission. In some instances, the luminophoric mediums disclosed herein can be formed from a combination of at least one luminescent material of the first and second types described in this paragraph. In implementations, the luminescent materials of the first type can emit light at a peak emission at about 515 nm, 525 nm, 530 nm, 535 nm, 540 nm, 545 nm, 550 nm, 555 nm, 560 nm, 565 nm, 570 nm, 575 nm, 580 nm, 585 nm, or 590 nm in response to the associated LED string emission. In preferred implementations, the luminescent materials of the first type can emit light at a peak emission between about 520 nm to about 555 nm. In implementations, the luminescent materials of the second type can emit light at a peak emission at about 590 nm, about 595 nm, 600 nm, 605 nm, 610 nm, 615 nm, 620 nm, 625 nm, 630 nm, 635 nm, 640 nm, 645 nm, 650 nm, 655 nm, 670 nm, 675 nm, 680 nm, 685 nm, 690 nm, 695 nm, or 700 nm in response to the associated LED string emission. In preferred implementations, the luminescent materials of the first type can emit light at a peak emission between about 600 nm to about 670 nm.

Some exemplary luminescent materials of the first and second type are disclosed elsewhere herein and referred to as Compositions A-F. Table 3 shows aspects of some exemplar luminescent materials and properties:

TABLE 3 Suitable Ranges Exemplary Emission Embodiment Peak Density Emission FWHM Range FWHM Designator Exemplary Material(s) (g/mL) Peak (nm) (nm) (nm) Range (nm) Composition Luag: Cerium doped 6.73 535 95 530-540  90-100 “A” lutetium aluminum garnet (Lu₃Al₅O₁₂) Composition Yag: Cerium doped yttrium  4.7 550 110 545-555 105-115 “B” aluminum garnet (Y₃Al₅O₁₂) Composition a 650 nm-peak wavelength  3.1 650 90 645-655 85-95 “C” emission phosphor: Europium doped calcium aluminum silica nitride (CaAlSiN₃) Composition a 525 nm-peak wavelength  3.1 525 60 520-530 55-65 “D” emission phosphor: GBAM: BaMgAl₁₀O₁₇:Eu Composition a 630 nm-peak wavelength  5.1 630 40 625-635 35-45 “E” emission quantum dot: any semiconductor quantum dot material of appropriate size for desired emission wavelengths Composition a 610 nm-peak wavelength  5.1 610 40 605-615 35-45 “F” emission quantum dot: any semiconductor quantum dot material of appropriate size for desired emission wavelengths Matrix “M” Silicone binder  1.1 mg/mm³

Blends of Compositions A-F can be used in luminophoric mediums (102A/102B/102C) to create luminophoric mediums having the desired saturated color points when excited by their respective LED strings (101A/101B/101C). In some implementations, one or more blends of one or more of Compositions A-F can be used to produce luminophoric mediums (102A/102B/102C). In some preferred implementations, one or more of Compositions A, B, and D and one or more of Compositions C, E, and F can be combined to produce luminophoric mediums (102A/102B/102C). In some preferred implementations, the encapsulant for luminophoric mediums (102A/102B/102C) comprises a matrix material having density of about 1.1 mg/mm³ and refractive index of about 1.545 or from about 1.4 to about 1.6. In some implementations, Composition A can have a refractive index of about 1.82 and a particle size from about 18 micrometers to about 40 micrometers. In some implementations, Composition B can have a refractive index of about 1.84 and a particle size from about 13 micrometers to about 30 micrometers. In some implementations, Composition C can have a refractive index of about 1.8 and a particle size from about 10 micrometers to about 15 micrometers. In some implementations, Composition D can have a refractive index of about 1.8 and a particle size from about 10 micrometers to about 15 micrometers. Suitable phosphor materials for Compositions A, B, C, and D are commercially available from phosphor manufacturers such as Mitsubishi Chemical Holdings Corporation (Tokyo, Japan), Intematix Corporation (Fremont, Calif.), EMD Performance Materials of Merck KGaA (Darmstadt, Germany), and PhosphorTech Corporation (Kennesaw, Ga.). In some implementations, a set of suitable materials for Compositions A-F and Matrix M can be selected, as shown in Table 4 as “Model 1”. In other implementations, a set of suitable materials for Compositions A-F and Matrix M can be selected, as shown in Table 4 as “Model 2.”

TABLE 4 Model 1 Model 2 Exemplary particle refractive particle refractive Designator Material(s) size (d50) index size index Composition “A” Luag: Cerium doped 18.0 μm 1.84 40 μm 1.8 lutetium aluminum garnet (Lu₃Al₅O₁₂) Composition “B” Yag: Cerium doped 13.5 μm 1.82 30 μm 1.85 yttrium aluminum garnet (Y₃Al₅O₁₂) Composition “C” a 650 nm-peak 15.0 μm 1.8 10 μm 1.8 wavelength emission phosphor: Europium doped calcium aluminum silica nitride (CaAlSiN₃) Composition “D” a 525 nm-peak 15.0 μm 1.8 n/a n/a wavelength emission phosphor: GBAM: BaMgAl₁₀O₁₇:Eu Composition “E” a 630 nm-peak 10.0 nm 1.8 n/a n/a wavelength emission quantum dot: any semiconductor quantum dot material of appropriate size for desired emission wavelengths Composition “F” a 610 nm-peak 10.0 nm 1.8 n/a n/a wavelength emission quantum dot: any semiconductor quantum dot material of appropriate size for desired emission wavelengths Matrix “M” Silicone binder 1.545 1.545

In some aspects, the present disclosure provides semiconductor light emitting devices 100 that can have a plurality of light emitting diode (LED) strings. Each LED string can have one, or more than one, LED. As depicted schematically in FIG. 8, the device 100 may comprise one or more LED strings (101A/101B/101C) that emit light (schematically shown with arrows) as in the device depicted in FIG. 1, with each LED string having a recipient luminophoric medium (102A/102B/102C) associated therewith, and the light emitted from the LED strings, combined with light emitted from the recipient luminophoric mediums, passed through one or more optical elements 103. The device 100 depicted in FIG. 8 differs from FIG. 1 in that an additional LED string 101D, having a recipient luminophoric medium 102D, is also present in the device 100. LED string 101D and luminophoric medium 102D can be a duplicate of one of LED strings 101A/101B/101C with mediums 102A/102B/102C. Accordingly, each device 100 depicted in FIG. 8 can have two white channels, one red channel, and one yellow/green channel, or each device can have one white channel, two red channels, and one yellow/green channel, or each device can have one white channel, one red channel, and two yellow/green channels.

In some aspects, the present disclosure provides semiconductor light emitting devices capable to producing tunable white light through a range of CCT values. In some implementations, devices can output white light at color points along a predetermined path within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3200K. In further implementations, devices can output white light at color points along a predetermined path shifted −7±2 DUV from the black body locus having a correlated color temperature between about 1800K and about 3200K. In some implementations, the devices can generate white light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90, R9 greater than or equal to about 55, and GAIBB greater than or equal to about 95. In some preferred implementations, the devices of the present disclosure can generate white light so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3000K, and generate the fifth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90, R9 greater than or equal to about 75, and GAIBB greater than or equal to about 95. In some implementations the devices of the present disclosure comprise a drive circuit is configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3200K, and in some of these implementations the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90 and R9 greater than or equal to about 55, one or more of Rf greater than or equal to 75, Rf greater than or equal to about 80, Rf greater than or equal to about 90, Rf greater than about 95, Rf equal to about 100, Rg greater than or equal to about 80 and less than or equal to about 120, Rg greater than or equal to about 90 and less than or equal to about 110, Rg greater than or equal to about 95 and less than or equal to about 105, or Rg equal to about 100. In some implementations the devices comprise a drive circuit configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3000K, and the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90 and R9 greater than or equal to about 60. In some implementations the devices comprise a drive circuit configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 2000K and about 3200K, and the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path with the light generated at each point having light with one or more of Rf greater than or equal to about 80, Rf greater than or equal to about 90, Rf greater than about 95, Rf equal to about 100, Rg greater than or equal to about 80 and less than or equal to about 120, Rg greater than or equal to about 85 and less than or equal to about 115; Rg greater than or equal to about 90 and less than or equal to about 110, Rg greater than or equal to about 95 and less than or equal to about 105, or Rg equal to about 100. In further implementations the devices comprise a drive circuit configured to adjust the fourth color point so that it falls within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3200K, and the light emitting devices are configured to generate the fourth unsaturated light corresponding to a plurality of points along a predefined path, with the light generated at points along about 85% of the predefined path has Ra greater than or equal to about 90, the light generated at points along about 85% of the predefined path has R9 greater than or equal to about 65, or both.

EXAMPLES General Simulation Method.

Devices having a plurality of LED strings with particular color points were simulated. For each device, LED strings and recipient luminophoric mediums with particular emissions were selected, and then white light rendering capabilities were calculated for a select number of representative points on or near the Planckian locus between about 1800K and about 3200K. Ra, R9, Rf, Rg, CLA, CS, EML, CAF, CER, and circadian performance values were calculated at each representative point, and COI values were calculated for representative points near the CCT range of about 3200K.

The calculations were performed with Scilab (Scilab Enterprises, Versailles, France), LightTools (Synopsis, Inc., Mountain View, Calif.), and custom software created using Python (Python Software Foundation, Beaverton, Oreg.). Each LED string was simulated with an LED emission spectrum and excitation and emission spectra of luminophoric medium(s). For luminophoric mediums comprising phosphors, the simulations also included the absorption spectrum and particle size of phosphor particles. The LED strings generating combined emissions within white, red, and yellow/green color regions were prepared using spectra of a LUXEON Z Color Line royal blue LED (product code LXZ1-PR01) of color bin codes 3, 4, 5, or 6 or a LUXEON Z Color Line blue LED (LXZ1-PB01) of color bin code 1 or 2 (Lumileds Holding B.V., Amsterdam, Netherlands). Similar LEDs from other manufacturers such as OSRAM GmbH and Cree, Inc. could also be used.

The emission, excitation and absorption curves are available from commercially available phosphor manufacturers such as Mitsubishi Chemical Holdings Corporation (Tokyo, Japan), Intematix Corporation (Fremont, Calif.), EMD Performance Materials of Merck KGaA (Darmstadt, Germany), and PhosphorTech Corporation (Kennesaw, Ga.). The luminophoric mediums used in the LED strings were combinations of one or more of Compositions A, B, and D and one or more of Compositions C, E, and F as described more fully elsewhere herein. Those of skill in the art appreciate that various combinations of LEDs and luminescent blends can be combined to generate combined emissions with desired color points on the 1931 CIE chromaticity diagram and the desired spectral power distributions.

Example 1

A semiconductor light emitting device was simulated having three LED strings. A first LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a white color point of (0.3818, 0.3797). A second LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a red color point with a 1931 CIE chromaticity diagram color point of (0.57, 0.387). A third LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a yellow/green color point with a 1931 CIE chromaticity diagram color point of (0.5107, 0.471).

Tables 5 and 6 below shows the spectral power distributions for the red and yellow-green color points generated by the device of this Example, with spectral power shown within wavelength ranges in nanometers from 380 nm to 780 nm, with an arbitrary reference wavelength range selected for each color range and normalized to a value of 100.0. Table 7 shows color-rendering and circadian performance characteristics of the device for a representative selection of white light color points near the Planckian locus.

TABLE 5 380-420 421-460 461-500 501-540 541-580 581-620 621-660 661-700 701-740 741-780 Red 0.1 2.7 4.3 9.5 24.6 60.4 100.0 51.5 12.4 2.4 Yag 0.2 0.8 3.5 41.2 72.5 93.9 100.0 47.6 12.2 2.6

TABLE 6 380-400 401-420 421-440 441-460 461-480 481-500 501-520 521-540 541-560 561-580 581-600 Red 0.1 0.1 0.7 4.5 4.9 3.5 6.7 11.6 17.6 30.0 48.9 Yellow- 0.3 0.1 0.2 1.2 1.7 5.1 28.1 51.9 63.3 77.5 89.3 Green 601-620 621-640 641-660 661-680 681-700 701-720 721-740 741-760 761-780 781-800 Red 67.9 93.5 100.0 66.0 33.7 16.5 7.6 3.2 1.5 0.0 Yellow- 93.0 100.0 94.2 60.8 31.7 16.0 7.7 3.5 1.6 0.0 Green

TABLE 7 White Yag Red Channel Channel Channel Relative Relative Relative CCT duv Intensity Intensity Intensity Ra R9 ccx ccy Rf 3202 −5.69 0.8704 0.231 0.37 89.4 59.4 0.42 0.383 84 3099 −5.78 0.7835 0.273 0.3893 89.9 62.1 0.42 0.385 85 3003 −5.56 0.7254 0.3312 0.4152 90.2 63.8 0.43 0.388 85 2904 −5.41 0.6155 0.357 0.4152 90.5 65.8 0.44 0.39 85 2803 −5.24 0.5444 0.399 0.441 90.9 67.9 0.44 0.393 84 2702 −5.35 0.483 0.4281 0.4798 91.5 70.7 0.45 0.394 84 2605 −5.51 0.4313 0.4572 0.5283 92.2 73.5 0.46 0.396 84 2499 −5.15 0.3667 0.5024 0.5735 92.6 75.2 0.47 0.398 84 2403 −5.44 0.3215 0.525 0.6414 93.4 78.0 0.48 0.398 84 2298 −5.37 0.2504 0.525 0.6704 94.0 80.0 0.49 0.399 83 2205 −5.74 0.2052 0.5218 0.7254 94.7 82.3 0.49 0.398 82 2105 −5.86 0.1502 0.5057 0.7577 95.2 83.8 0.5 0.397 81 1998 −5.45 0.0921 0.4992 0.7868 95.5 84.0 0.51 0.397 80 1887 −5.72 0.0468 0.4604 0.8126 95.5 84.5 0.53 0.394 78 1773 −5.38 0 0.4216 0.8126 95.3 83.1 0.54 0.392 76 circadian power circadian CCT Rg COI [mW] flux CER CAF EML CLA CS 3202 104 3.76 0.081 0.024 128.222 0.443 0.561 444 0.393 3099 104 0.076 0.022 121.755 0.424 0.543 1018 0.533 3003 104 0.072 0.020 115.192 0.404 0.523 978 0.527 2904 105 0.067 0.019 108.451 0.384 0.503 938 0.521 2803 105 0.062 0.017 101.368 0.363 0.482 895 0.514 2702 106 0.058 0.015 94.782 0.345 0.462 858 0.508 2605 107 0.053 0.014 88.455 0.328 0.444 821 0.501 2499 108 0.049 0.012 80.647 0.304 0.419 772 0.491 2403 109 0.044 0.011 74.628 0.288 0.400 737 0.483 2298 110 0.040 0.009 67.530 0.267 0.377 692 0.473 2205 111 0.036 0.008 62.105 0.253 0.360 658 0.464 2105 112 0.033 0.007 55.891 0.234 0.338 617 0.453 1998 113 0.029 0.006 48.569 0.210 0.310 563 0.437 1887 116 0.025 0.005 42.491 0.192 0.286 519 0.422 1773 118 0.021 0.004 35.558 0.168 0.256 462 0.4

Table 8 shows exemplary luminophoric mediums suitable for the recipient luminophoric mediums for the red and yellow/green channels of this Example, using the Compositions A-F from Model 1 or Model 2 as described in Tables 3 and 4.

TABLE 8 Volumetric Ratios - Using “Model 1” Compositions from Tables 3 and 4 Comp. A Comp. B Comp. C Comp. D Comp. E Comp. F Matrix Red Blend 1 13.99 26.57 59.44 Red Blend 2 17.20 8.94 73.86 Red Blend 3 20.56 18.38 0.02 61.04 Red Blend 4 5.55 9.40 22.00 63.05 Red Blend 5 2.47 29.16 47.28 21.08 Yag Blend 1 40.66 15.33 44.01 Yag Blend 2 16.68 12.18 5.87 65.27 Yag Blend 3 6.96 16.57 76.47 Yag Blend 4 17.49 9.61 24.75 48.14 Yag Blend 5 28.20 6.85 14.62 50.33 Yag Blend 6 53.05 5.16 19.36 22.43

Light rendering properties were calculated for commercially available tunable white light systems. Table 9 shows color-rendering and circadian performance characteristics of a three-channel device having white, green, and red channels, LED Engin's LuxiTune™ Tunable White Light Engine For Halogen-style Dimming LTC-83T1xx-0HD1 (LED Engin, Inc., San Jose, Calif.), for a representative selection of white light color points near the Planckian locus. Table 10 shows color-rendering and circadian performance characteristics of a five-channel device having white, blue, red, lime, and amber channels, Lumenetix's Araya® Color Tuning Module (CTM) (Lumenetix, Scotts Valley, Calif.), for a representative selection of white light color points near the Planckian locus.

TABLE 9 circadian power circadian CCT duv Ra R9 Rf Rg [mW] flux CER CAF EML CLA CS 2957.1 −0.99 88.14 60.12 87 109 0.001 0.0003 113.4262 0.3585 0.49788 914 0.517 2832.5 −1.11 87.55 58.33 87 109 0.001 0.0002 106.4456 0.3361 0.4747 868 0.509 2741.4 −0.58 87.23 58.96 87 110 0.001 0.0002 99.9416 0.3140 0.45283 824 0.501 2608.7 −0.52 86.92 60.56 86 111 0.001 0.0002 92.4105 0.2885 0.42649 772 0.491 2506.3 −0.26 86.69 62.57 86 111 0.001 0.0001 85.8899 0.2670 0.40442 727 0.481 2303.2 −0.25 85.21 65.65 85 112 0.000 0.0001 74.0231 0.2303 0.36621 652 0.463 2040.7 −2.87 80.84 66.23 80 106 0.000 0.0000 64.8177 0.2083 0.33513 595 0.447 1901.4 −3.36 79.19 71.22 77 118 0.000 0.0000 58.1408 0.1897 0.31196 552 0.433 1782.2 1.95 82.13 92.16 78 99 0.000 0.0000 39.1467 0.1230 0.24983 425 0.384

TABLE 10 circadian power circadian CCT duv Ra R9 Rf Rg [mW] flux CER CAF EML CLA CS 2977 −0.25 96.09 90.52 93 104 0.001 0.0003 116.7513 0.3865 0.55372 1011 0.532 2872 −1.82 96.90 96.13 94 104 0.001 0.0003 111.6608 0.3787 0.54171 991 0.529 2744 −1.99 97.00 88.16 93 103 0.001 0.0002 104.3151 0.3520 0.50898 929 0.52 2560 −0.56 96.61 89.42 93 104 0.001 0.0001 90.5068 0.3020 0.45693 825 0.502 2454 −0.64 95.93 94.25 93 104 0.000 0.0001 84.5877 0.2838 0.43942 790 0.495 2287 −1.48 95.11 93.38 90 106 0.000 0.0001 76.2707 0.2567 0.40294 722 0.48 2011 0.81 93.56 93.09 89 101 0.000 0.0000 55.2737 0.1859 0.33012 578 0.441 1834 2.10 90.64 83.00 82 90 0.000 0.0000 43.3134 0.1437 0.2831 484 0.41

Example 2

A semiconductor light emitting device was simulated having three LED strings. A first LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a white color point of (0.3818, 0.3797). A second LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a red color point with a 1931 CIE chromaticity diagram color point of (0.57, 0.387). A third LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a yellow/green color point with a 1931 CIE chromaticity diagram color point of (0.5107, 0.471).

Tables 11 and 12 below shows the spectral power distributions for the red and yellow-green color points generated by the device of this Example, with spectral power shown within wavelength ranges in nanometers from 380 nm to 780 nm, with an arbitrary reference wavelength range selected for each color range and normalized to a value of 100.0. Table 13 shows color-rendering and circadian performance characteristics of the device for a representative selection of white light color points near the Planckian locus.

TABLE 11 380-420 421-460 461-500 501-540 541-580 581-620 621-660 661-700 701-740 741-780 Red 0.0 2.3 5.0 10.2 24.7 61.0 100.0 71.7 27.8 8.4 Yag 0.2 0.9 5.0 58.9 100.0 129.4 140.5 91.6 35.3 10.5 380-500 501-600 601-700 701-780 Red 3.5 28.2 100.0 17.3 Yag 2.0 73.4 100.0 15.3

TABLE 12 380-400 401-420 421-440 441-460 461-480 481-500 501-520 521-540 541-560 561-580 581-600 Red 0.0 0.0 0.4 4.1 5.8 4.0 7.2 12.7 18.9 29.4 46.9 Yellow- 0.2 0.1 0.2 1.1 1.7 5.2 28.7 52.9 63.5 74.8 85.0 Green 601-620 621-640 641-660 661-680 681-700 701-720 721-740 741-760 761-780 781-800 Red 72.4 95.7 100.0 83.0 57.2 34.7 19.7 10.8 5.7 0.0 Yellow- 94.1 100.0 94.4 75.4 51.3 31.1 17.7 9.6 5.0 0.2 Green

TABLE 13 White Yag Red Channel Channel Channel Relative Relative Relative CCT duv Intensity Intensity Intensity Ra R9 ccx ccy Rf 3204 −5.43 1 0.0856 0.5121 89.1 54.8 0.42 0.383 85 3100 −5.21 0.7997 0.1244 0.4701 89.4 56.8 0.42 0.386 85 3005 −5.51 0.7092 0.1341 0.4927 90.0 59.7 0.43 0.388 85 2907 −5.42 0.6381 0.1632 0.5185 90.5 61.9 0.44 0.39 85 2807 −5.2 0.5832 0.1986 0.5606 90.9 63.8 0.44 0.393 85 2703 −5.19 0.525 0.2181 0.6123 91.5 66.1 0.45 0.395 86 2600 −5.21 0.4572 0.2246 0.6543 92.1 68.2 0.46 0.396 86 2505 −5.1 0.3861 0.2246 0.6737 92.6 69.9 0.47 0.398 86 2403 −5.33 0.3279 0.2084 0.7157 93.3 71.9 0.48 0.398 86 2307 −5.54 0.273 0.1858 0.7415 93.8 73.4 0.48 0.398 85 2200 −5.2 0.2246 0.1858 0.8061 94.2 74.0 0.49 0.399 85 2104 −5.83 0.189 0.1438 0.8546 94.5 75.0 0.5 0.397 85 2003 −5.23 0.1438 0.1373 0.9063 94.5 74.2 0.51 0.398 84 1900 −5.24 0.1018 0.0985 0.9063 94.3 73.2 0.53 0.396 83 1773 −5.48 0.0695 0.501 1 93.3 70.7 0.54 0.392 81 circadian power circadian CCT Rg COI [mW] flux CER CAF EML CLA CS 3204 103 3.86 0.081 0.024 128.182 0.443 0.564 444 0.393 3100 103 3.98 0.077 0.022 120.974 0.422 0.544 1019 0.533 3005 104 0.073 0.021 115.186 0.407 0.529 989 0.529 2907 104 0.069 0.019 108.461 0.388 0.510 951 0.523 2807 104 0.064 0.017 101.323 0.367 0.490 910 0.517 2703 105 0.060 0.016 94.359 0.348 0.470 870 0.51 2600 106 0.055 0.014 87.509 0.329 0.450 831 0.503 2505 106 0.051 0.013 80.996 0.310 0.430 792 0.495 2403 107 0.047 0.012 74.788 0.293 0.411 756 0.488 2307 108 0.043 0.010 69.068 0.277 0.393 721 0.48 2200 108 0.038 0.009 61.677 0.254 0.368 673 0.468 2104 109 0.035 0.008 57.078 0.242 0.353 645 0.461 2003 109 0.031 0.007 50.020 0.218 0.327 594 0.446 1900 110 0.027 0.006 44.302 0.200 0.305 553 0.433 1773 112 0.023 0.005 38.022 0.180 0.279 505 0.417

Example 3

A semiconductor light emitting device was simulated having three LED strings. A first LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a white color point of (0.3818, 0.3797). A second LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a red color point with a 1931 CIE chromaticity diagram color point of (0.5842, 0.3112). A third LED string is driven by a blue LED having peak emission wavelength of approximately 450 nm to approximately 455 nm, utilizes a recipient luminophoric medium, and generates a combined emission of a yellow/green color point with a 1931 CIE chromaticity diagram color point of (0.5108, 0.4708).

Tables 14 and 15 below shows the spectral power distributions for the red and yellow-green color points generated by the device of this Example, with spectral power shown within wavelength ranges in nanometers from 380 nm to 780 nm, with an arbitrary reference wavelength range selected for each color range and normalized to a value of 100.0. Table 16 shows color-rendering and circadian performance characteristics of the device for a representative selection of white light color points near the Planckian locus.

TABLE 14 380-420 421-460 461-500 501-540 541-580 581-620 621-660 661-700 701-740 741-780 Red 0.03 100.00 1.27 0.88 5.73 30.73 63.36 46.34 18.67 5.68 Yag 0.00 0.68 2.90 39.05 69.00 85.14 100.00 61.26 23.71 7.23 380-500 501-600 601-700 701-780 Red 5.67 12.58 100.00 18.65 Yag 1.72 70.44 100.00 14.88

TABLE 15 380-400 401-420 421-440 441-460 461-480 481-500 501-520 521-540 541-560 561-580 581-600 Red 0.0 0.1 3.9 14.9 3.4 0.5 0.8 2.0 5.8 11.8 30.2 Yellow- 0.0 0.0 0.1 1.2 2.3 3.3 23.1 51.6 64.5 67.5 73.5 Green 601-620 621-640 641-660 661-680 681-700 701-720 721-740 741-760 761-780 781-800 Red 64.2 94.6 100.0 83.6 58.7 36.3 21.0 11.4 6.0 0.0 Yellow- 89.3 100.0 91.3 70.0 47.1 28.8 16.6 9.1 4.8 0.0 Green

TABLE 16 White Yag Red Channel Channel Channel Relative Relative Relative CCT duv Intensity Intensity Intensity Ra R9 ccx ccy Rf 3200 −5.17 1 0.2892 0.3829 89.1 58.5 0.42 0.384 84 3103 −5.18 1 0.3764 0.4443 89.6 61.5 0.42 0.386 84 2993 −5.37 1 0.4766 0.538 90.3 65.3 0.43 0.388 84 2900 −5.39 1 0.5832 0.6317 90.8 68.0 0.44 0.39 84 2806 −5.54 1 0.6963 0.7544 91.4 71.0 0.44 0.392 84 2711 −5.45 1 0.8514 0.9031 91.8 73.4 0.45 0.394 84 2602 −5.74 0.8805 0.8966 1 92.6 76.6 0.46 0.395 84 2501 −5.86 0.706 0.8643 1 93.2 79.0 0.47 0.396 84 2402 −5.67 0.5574 0.8514 1 93.7 80.8 0.48 0.397 83 2305 −5.82 0.4346 0.7997 1 94.3 82.5 0.48 0.397 83 2200 −5.77 0.3215 0.7544 1 94.8 83.7 0.49 0.398 82 2103 −5.36 0.2278 0.7286 1 95.0 84.0 0.5 0.398 81 2000 −5.52 0.1535 0.6606 1 95.2 84.1 0.51 0.397 79 1900 −5.91 0.0985 0.5864 1 95.0 83.4 0.52 0.394 77 1775 −5.37 0.0307 0.5343 1 94.8 80.6 0.54 0.392 75 circadian power circadian CCT Rg COI [mW] flux CER CAF EML CLA CS 3200 104 3.67 0.079 0.023 126.320 0.437 0.555 429 0.386 3103 104 3.86 0.075 0.021 119.814 0.419 0.537 1006 0.531 2993 105 0.070 0.020 112.679 0.400 0.518 967 0.526 2900 105 0.066 0.018 106.398 0.382 0.500 932 0.52 2806 106 0.062 0.017 100.219 0.365 0.482 897 0.514 2711 106 0.057 0.015 93.562 0.346 0.462 857 0.508 2602 108 0.053 0.014 86.684 0.328 0.442 818 0.5 2501 109 0.048 0.012 80.094 0.309 0.421 778 0.492 2402 109 0.044 0.011 73.082 0.288 0.398 733 0.483 2305 111 0.040 0.010 66.976 0.270 0.378 694 0.473 2200 112 0.036 0.008 60.154 0.249 0.354 648 0.462 2103 112 0.033 0.007 53.261 0.226 0.328 598 0.448 2000 114 0.029 0.006 47.375 0.208 0.305 555 0.434 1900 116 0.026 0.005 42.352 0.193 0.284 516 0.421 1775 118 0.022 0.004 34.549 0.165 0.249 450 0.395

Tables 17 and 18 show exemplary luminophoric mediums suitable for the recipient luminophoric mediums for the red and yellow/green channels of this Example, using the Compositions A-F from Model 1 or Model 2 as described in Tables 3 and 4.

TABLE 17 Volumetric Ratios - Using “Model 1” Compositions from Tables 3 and 4 Comp. A Comp. B Comp. C Comp. D Comp. E Comp. F Matrix Red Blend 1 1.66 24.23 74.11 Red Blend 2 0.07 15.34 7.90 76.70 Red Blend 3 1.96 24.72 73.32 Red Blend 4 3.43 26.48 70.10 Red Blend 5 21.36 1.70 76.94 Red Blend 6 0.80 24.49 1.22 73.49 Red Blend 7 0.22 12.74 11.75 75.28 Yellow/Green Blend 1 50.54 0.02 49.44 Yellow/Green Blend 2 37.70 1.40 0.61 60.28 Yellow/Green Blend 3 43.22 15.08 41.70 Yellow/Green Blend 4 6.51 19.90 73.59 Yellow/Green Blend 5 5.01 15.89 37.71 41.39 Yellow/Green Blend 6 24.41 9.45 11.02 55.11

TABLE 18 Volumetric Ratios - Using “Model 2” Compositions from Tables 3 and 4 Comp. A Comp. B Comp. C Comp. D Comp. E Comp. F Matrix Red Blend 8 0 0.58 16.23 83.19 Red Blend 9 0.42 0 16.63 82.95 Red Blend 10 1.79 3.09 17.6 77.52

Example 4

Exemplary luminophoric mediums suitable for the recipient luminophoric mediums for the red and yellow/green channels of the disclosure were modeled, using the Compositions A-F from Model 1 or Model 2 as described in Tables 3 and 4. Tables 19 and 20 show exemplary suitable luminophoric mediums that can be used in the red and yellow/green channels.

TABLE 19 Volumetric Ratios - Using “Model 1” Compositions from Tables 3 and 4 Comp. A Comp. B Comp. C Comp. D Comp. E Comp. F Matrix Red Blend 11.66 21.77 66.57 Red Blend 5.59 17.46 7.21 69.74 Red Blend 13.17 25.45 61.38 Red Blend 6.47 7.75 24.90 60.88 Red Blend 16.55 8.34 75.11 Red Blend 2.37 24.60 11.89 61.13 Red Blend 4.57 16.51 12.47 66.44 Red Blend 2.18 20.26 77.55 Red Blend 0.40 13.83 5.57 80.20 Red Blend 2.57 20.93 76.50 Red Blend 0.68 2.15 22.07 75.10 Red Blend 17.50 2.11 80.40 Red Blend 1.62 20.45 0.85 77.07 Red Blend 0.47 11.38 9.48 78.67 Red Blend 2.12 26.06 71.82 Red Blend 0.24 16.36 9.03 74.37 Red Blend 2.43 26.68 70.89 Red Blend 1.02 1.64 28.61 68.72 Red Blend 22.60 2.22 75.19 Red Blend 1.11 26.37 1.45 71.07 Red Blend 0.38 13.79 12.99 72.84 Yellow/Green Blend 54.92 1.82 43.26 Yellow/Green Blend 56.18 3.90 0.07 39.86 Yellow/Green Blend 2.49 20.51 77.00 Yellow/Green Blend 5.21 5.34 46.86 42.59 Yellow/Green Blend 38.63 1.55 1.84 57.98 Yellow/Green Blend 16.75 2.44 80.81 Yellow/Green Blend 32.98 8.23 0.06 58.73 Yellow/Green Blend 2.90 7.46 89.64 Yellow/Green Blend 0.79 4.25 17.43 77.53 Yellow/Green Blend 10.62 1.98 2.24 85.17 Yellow/Green Blend 46.13 3.33 50.54 Yellow/Green Blend 74.85 15.25 0.09 9.81 Yellow/Green Blend 2.99 18.14 78.87 Yellow/Green Blend 5.55 5.59 38.75 50.11 Yellow/Green Blend 32.93 2.40 3.11 61.56 Yellow/Green Blend 42.76 1.82 55.43 Yellow/Green Blend 44.06 3.54 0.05 52.35 Yellow/Green Blend 2.60 16.60 80.80 Yellow/Green Blend 3.59 4.91 38.01 53.50 Yellow/Green Blend 30.44 1.49 1.87 66.20

TABLE 20 Volumetric Ratios - Using “Model 2” Compositions from Tables 3 and 4 Comp. A Comp. B Comp. C Comp. D Comp. E Comp. F Matrix Red Blend 4.02 13.36 82.62 Red Blend 3.25 15.67 81.08 Red Blend 16.56 15.37 16.88 51.19 Red Blend 0.74 14.13 85.13 Red Blend 0.6 14.65 84.75 Red Blend 3.07 3.52 14.75 78.66 Red Blend 0.74 17.04 82.22 Red Blend 0.58 17.52 81.90 Red Blend 2.3 3.97 18.94 74.79 Yellow/Green Blend 94.48 0.04 3.51 1.97 Yellow/Green Blend 39.09 3.06 1.16 56.69

Those of ordinary skill in the art will appreciate that a variety of materials can be used in the manufacturing of the components in the devices and systems disclosed herein. Any suitable structure and/or material can be used for the various features described herein, and a skilled artisan will be able to select an appropriate structures and materials based on various considerations, including the intended use of the systems disclosed herein, the intended arena within which they will be used, and the equipment and/or accessories with which they are intended to be used, among other considerations. Conventional polymeric, metal-polymer composites, ceramics, and metal materials are suitable for use in the various components. Materials hereinafter discovered and/or developed that are determined to be suitable for use in the features and elements described herein would also be considered acceptable.

When ranges are used herein for physical properties, such as molecular weight, or chemical properties, such as chemical formulae, all combinations, and subcombinations of ranges for specific exemplar therein are intended to be included.

The disclosures of each patent, patent application, and publication cited or described in this document are hereby incorporated herein by reference, in its entirety.

Those of ordinary skill in the art will appreciate that numerous changes and modifications can be made to the exemplars of the disclosure and that such changes and modifications can be made without departing from the spirit of the disclosure. It is, therefore, intended that the appended claims cover all such equivalent variations as fall within the true spirit and scope of the disclosure. 

What is claimed:
 1. A method of generating white light, the method comprising: producing light from a first light emitting diode (“LED”) string that comprises a blue LED with a peak wavelength of between about 405 nm and about 470 nm; producing light from a second light emitting diode (“LED”) string that comprises a blue LED with a peak wavelength of between about 405 nm and about 470 nm; producing light from a third light emitting diode (“LED”) string that comprises a blue LED with a peak wavelength of between about 405 nm and about 470 nm; passing the light produced by each of the first, second, and third LED strings through one of a plurality of respective luminophoric mediums to produce a first unsaturated light, a second unsaturated light, and a third unsaturated light, respectively; combining the first unsaturated light, the second unsaturated light, and the third unsaturated light together into a fourth unsaturated light; wherein the first unsaturated light has a first color point within a white color range defined by a polygonal region on the 1931 CIE Chromaticity Diagram defined by the following ccx, ccy color coordinates: (0.4006, 0.4044), (0.3736, 0.3874), (0.3670, 0.3578), (0.3898, 0.3716); wherein the second unsaturated light has a second color point within a red color range defined by the spectral locus between the constant CCT line of 1600K and the line of purples, the line of purples, a line connecting the ccx, ccy color coordinates (0.61, 0.21) and (0.47, 0.28), and the constant CCT line of 1600K; wherein the third unsaturated light has a third color point within a yellow/green color range defined by the constant CCT line of 4600K, the Planckian locus between 4600K and 550K, the spectral locus, and a line connecting the ccx, ccy color coordinates (0.445, 0.555) and (0.38, 0.505); and wherein fourth unsaturated light corresponds to at least one of a plurality of points along a predefined path near the black body locus in the 1931 CIE Chromaticity Diagram within a 7-step MacAdam ellipse around any point on the black body locus having a correlated color temperature between about 1800K and about 3200K.
 2. The method of claim 1, wherein the white color range comprises a single 5-step MacAdam ellipse with center point (0.3818, 0.3797) with a major axis “a” of 0.01565, minor axis “b” of 0.00670, with an ellipse rotation angle θ of 52.70° relative to a line of constant ccy values.
 3. The method of claim 1, wherein the red color range comprises a region on the 1931 CIE Chromaticity Diagram defined by a 20-step MacAdam ellipse at 1200K, 20 points below the Planckian locus.
 4. The method of claim 1, wherein the yellow/green color range comprises a region on the 1931 CIE Chromaticity Diagram defined by a 16-step MacAdam ellipse at 3700K, 30 points above Planckian locus.
 5. The method of claim 1, wherein the white color range comprises a single 3-step MacAdam ellipse with center point (0.3818, 0.3797) with a major axis “a” of 0.00939, minor axis “b” of 0.00402, with an ellipse rotation angle θ of 53.7° relative to a line of constant ccy values.
 6. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path with the light generated at each point having light with one or more of Rf greater than or equal to about 85, Rg greater than or equal to about 85 and less than or equal to about
 115. 7. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path with the light generated at each point having light with one or more of Rf greater than or equal to about 80, Rg greater than or equal to about 80 and less than or equal to about
 120. 8. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path with the light generated at each point having light with one or more of Rf greater than or equal to about 80, Rg greater than or equal to about 100 and less than or equal to about
 112. 9. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path with the light generated at each point having light with one or more of: Rf greater than or equal to about 80; and Rg greater than or equal to about 103 and less than or equal to about
 112. 10. The method of claim 1, wherein the second unsaturated light has a spectral power distribution that falls between the red minimum and red maximum ranges shown in Table
 2. 11. The method of claim 1, wherein the third unsaturated light has a spectral power distribution that falls between the yellow/green minimum and yellow/green maximum ranges shown in Table
 2. 12. The method of claim 1, wherein the second unsaturated light has a spectral power distribution that falls between the Red 7 and Red 8 ranges shown in Table
 2. 13. The method of claim 1, wherein the third unsaturated light has a spectral power distribution that falls between the Yellow/Green 7 and Yellow/Green 8 ranges shown in Table
 2. 14. The method of claim 1, wherein the method further comprises receiving input from one or more of an end user of the semiconductor light emitting device and one or more sensors measuring a characteristic associated with the performance of the first LED, the second LED, or the third LED.
 15. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path, wherein: the light generated at points along about 85% of the predefined path has Rf greater than or equal to about 84; the light generated at points along about 85% of the predefined path has Rg greater than or equal to about 95 and less than or equal to about 110; or both.
 16. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path with the light generated at each point having light with one or more of Ra greater than or equal to about 90, R9 greater than or equal to about
 55. 17. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path with the light generated at each point having light with one or more of: Ra greater than or equal to about 89; and R9 greater than or equal to about
 59. 18. The method of claim 1, wherein the method comprises generating fourth unsaturated light corresponding to a plurality of points along the predefined path, wherein: the light generated at points along about 85% of the predefined path has Ra greater than or equal to about 90; the light generated at points along about 85% of the predefined path has R9 greater than or equal to about 65; or both. 